The Theoretical Description for Sulfite and Nitrite Anodic Detection and Removal from Wine over Poly(9- Triphenylphosphazo)Acridine-Modified Electrode
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Volodymyr V. Tkach, Marta V. Kushnir , Natalia S. Andrusyak, Yana G. Ivanushko , Oleksandra V. Ahafonova , Petro I. Yagodynets , Lyudmyla V. Romaniv , Adriano O. da Silva , Nataliia P. Derevyanko , Oksana V. Kobets , Mykhailo P`. Zavhorodnii , Vira M. Odyntsova
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Abstract
A novel electroanalytical process for nitrite and sulfite anodic electrochemical determination
in wine, based on the 9-triphenylphosphazoacridine conducting polymer as an anode modifier, has been
investigated. 9-triphenylphosphazoacridine monomer may be obtained from 9-chloroacridine via 9-
azidoacridine by reacting it with triphenylphosphine in ether. As for the sulfite and nitrite
electrooxidation to sulfate and nitrate correspondently is given in conducting polymer matrix by two
doping types. The analysis of the model has confirmed the efficiency of poly(9-
triphenylphosphazo)acridine as an electrode modifier for sulfite and nitrite determination in wine,
although the oscillatory behavior is relatively probable.